High‐Tg Carbazole Derivatives as Blue‐Emitting Hole‐Transporting Materials for Electroluminescent Devices

A series of dicarbazolyl derivatives bridged by various aromatic spacers and decorated with peripheral diarylamines were synthesized using Ullmann and Pd‐catalyzed C–N coupling procedures. These derivatives emit blue light in solution. In general, they possess high glass‐transition temperatures (T_g > 125 °C) which vary with the bridging segment and methyl substitution on the peripheral amine. Double‐layer organic light‐emitting devices were successfully fabricated using these molecules as hole‐transporting and emitting materials. Devices of the configuration ITO/HTL/TPBI/Mg:Ag (ITO: indium tin oxide; HTL: hole‐transporting layer; TPBI: 1,3,5‐tris(N‐phenylbenzimidazol‐2‐yl)benzene) display blue emission from the HTL layer. The EL spectra of these devices appear slightly distorted due to the exciplex formation at the interfaces. However, for the devices of the configuration ITO/HTL/Alq₃/Mg:Ag (Alq₃ = tris(8‐hydroxyquinoline)aluminum) a bright green light from the Alq₃ layer was observed. This clearly demonstrates the facile hole‐transporting property of the materials described here.     

VARIATIONS IN ALFALFA JUICE SOLUTE CONCENTRATIONS AS WATER IS EVAPORATED

Alfalfa juice was extracted from plants during the graving phases of the first and second crops. The alfalfa juice was dried and solute concentrations were measured periodically during the process using freezing point depression (FPD) as an indicator. Solute/solvent weight ratios were calculated from the freezing point depression of fresh unconcentrated 'uice extracted from both firsc and second crops. At the time of harvest, tie FPD was a function of this ratio. The first and second crops behaved distinctively different during the drying process, with the second having a larger soluce concentration and a greater FPD at a given moisture content. The appearance of preci itate during the drying process and the general1 large FPD makes this materiay a questionable product for drying vitg low temperature processes.     

Simulation of runoff and phosphorus transport in a Carpathian catchment,Slovakia

A comprehensive, GIS‐based modelling approach is developed to estimate runoff and phosphorus transport within a watershed at a daily time step. The approach relies on the use of GIS data for deriving major critical model parameters that exhibit distinct spatial variability over the catchment. Surface runoff is calculated by a modified rational method, which depends upon rainfall intensity, soil moisture status, slope, land‐use and soil characteristics. Phosphorus loading is estimated as a function of the runoff volume and the event mean concentration for different land use categories. A diffusive approximation method is used to trace runoff and phosphorus transport to the basin outlet. The modelling approach is tested in the Margecany catchment, Hornad River basin, Slovakia, to simulate runoff, phosphorus loading, and its transport on a daily time scale using data observed between 1995 and 2000. Satisfactory results of the hydrographs and phosphorus concentration at the basin outlet are obtained, though more efforts regarding the phosphorus cycling and its biochemical reactions need to be clarified by further research. Copyright © 2006 John Wiley & Sons, Ltd.     

油气输导体系的类型及配置关系

将输导体系划分为储集层输导体系、断裂输导体系和不整合输导体系3大类，8种类型，指出输导体系的时空配置关系是决定油气藏的重要因素；着重阐明了输导层在空间和时间上的配置关系，认为这些配置关系是影响输导体系有效性的重要因素；提出了运移级次性的概念，讨论了划分运移级次对油气运移研究的意义，指出准噶尔盆地西北缘邻近玛湖以储集层输导体系和不整合输导体系为主．边缘地区以断层输导体系为主。浅层油气成藏期主要取决于断层的活动期。     

The Influence of Medium on Low-Voltage Circuit Breaker Arcs

This paper mainly focuses on the influence of three kinds of media： air, air-10%PA （Nylon） and air-10% POM （polyoxymethylene） on low-voltage circuit breaker arcs. A threedimensional （3-D） model of arc motioa under the effect of external magnetic field is built based on magnetohydrodynamics （MHD） equations. By adopting the commercial computational fluid dynamics （CFD） package based on the control-volume method, the above MHD equations are solved. For the media of air-10%PA and air-10%POM, the distributions of stationary temperature and electrical potential and the transient motion processes are compared with those of air arc. The research shows that both air-10%PA and air -10% POM can cool the arc plasma and the former is more effective. Both of them can increase the stationary voltage as well. Moreover, the presence of the two mixtures can accelerate the arc motion toward the quenching area and ensures the arc quenched in time.     

Water and salt permeability of reinforcement polymer‐gel composite membrane

The charged mosaic polymer membrane (CMM) without reinforcement and the composite charged mosaic polymer membrane (CCMM) with reinforcement were investigated in terms of salt and water transport (permeability). The composite charged mosaic polymer membrane (CCMM) with reinforcement showed a unique transport behavior such as preferential material transport L_p and ω. Water permeability coefficient, L_p and salt permeability coefficient, ω were estimated by taking account of active layer thickness of composite polymer gel. The L_p and ω values of CCMM with reinforcement were larger than those of CMM without reinforcement. On the other hand, the reflection coefficient of CCMM, σ, showed negative value, which suggested preferential material transport to solvent transport. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

油煤浆的管道输送特性与管路设计原则

通过理论分析和管道实验，探讨了油煤浆在工业管道输送中的流变特性、流动状态和阻力特性，得出了油煤浆的物性参数、表观参数、管道阻力参数的测定值和计算公式，并在此基础上探讨了油煤浆管道输送的设计原则，为油煤浆管路的设计提供基础数据、计算方法和一般原则。     

The desorption of O2 during NO and N2O decomposition on Cu- and Fe-zeolites

The decomposition of NO and of N₂O over a CuZSM-5 zeolite and a Fe-mordenite, respectively, has been studied using tracer techniques. The results demonstrate the high mobility of the lattice oxygen ions in self-diffusion. They afford a possible explanation for the problem of how two extralattice oxygens located at positions remote from each other may combine to form the O₂ molecules which are spontaneously desorbed in these redox reactions. They show that a portion of the lattice oxygen mixes into the O₂ released on decomposition. The data also show that N¹⁸O and N₂ ¹⁸O undergo exchange with the catalyst oxygen under reaction conditions.On leave from Central Research Institute for Chemistry, Hungarian Academy of Sciences, H-1525 Budapest, Hungary.